Applicability and potential of polymer injection as an EOR technique for Lower Miocene reservoir in Bach Ho field
Abstract
Polymer for EOR is prepared by radiation techniques. The polymer is synthesised by gamma radiation copolymerisation of acrylamide/or sodium acrylate and N-vinyl pyrrolidone which are hydrophilic monomers. The polymerisation extent and its molecular weight depend on the parameters consisting of radiation dose, dose rate, concentrations of co-monomer and monomer-type. The yield of product is almost 100% when acrylamide is used, higher than using sodium acrylate (~ 71%). The obtained polymer dissolves well not only in water but in brine also. The polymer was not precipitated in hard brines at high temperature (>120oC) and its viscosity slightly reduced around 20% after heating for 30 days at 120oC. The features of polymer including thermal stability, rheology and efficiency of oil recovery were determined. The EOR coefficient of the studied polymer solution was evaluated by the modelling instrument, at submerged oil-well condition. The results show the EOR coefficient enhanced by 12.1% and it satisfies under the condition of Lower Miocene reservoir in Bach Ho oilfield. On the basis of tested results combined with simulation calculations, the economic efficiency of injection technology of radiation-modified polymer solution has also been discussed.
References
David J.Pye. Improved secondary recovery by control of water mobility. Journal of Petroleum Technology. 1964; 16(8): p. 911 - 916.
R.H.Christopher, Stanley Middleman.Power-law flow through a packed tube. Industrial & Engineering Chemistry Fundamentals. 1965; 4(4): p. 422 - 426.
D.L.Dauben, D.E.Menzie. Flow of polymer solutions through porous media. Journal of Petroleum Technology. 1967; 19(8): p. 1065 - 1073.
R.L.Jewett, G.F.Schurz. Polymer flooding - A current appraisal. Journal of Petroleum Technology. 1970; 22(6): p. 675 - 684.
J.F.Stanislav. Use of polymers in oil recovery process. Progress and Trends in Rheology. 1982: p.210 - 211.
G.D.Khune, L.G.Donaruma, M.J.Hatch, N.H.Kilmer, J.S.Shepitka, F.D.Martin. Modifi ed acrylamide polymers for enhanced oil recovery.Journal of Applied Polymer Science. 1985; 30(2): p. 875 - 885.
C.L.McCormick, K.P.Blackmon. Water-soluble copolymers - XII: Copolymers of acrylamide with sodium-3-acrylamido-3-methylbutanoate: Synthesis and characterization. Journal of Polymer Science - Part A: Polymer Chemistry. 1986; 24(10): p. 2635 - 2645.
D.L.Dauben, D.E.Menzie. Flow of polymer solutions through porous media. Journal of Petroleum Technology. 1967; 19(8): p. 1065 - 1703.
I.Shvetsov, G.Bakaev, V.Kabo, V.Perunov, Yu.Soliakov. The current state and prospects of the method of polymer strata stimulation application. Oil Industry. 1994: p. 41 - 44.
Kevin C.Taylor, Hisham A.Nasr-El-Din. Acrylamide copolymers: A review of methods for the determination of concentration and degree of hydrolysis. Journal of Petroleum Science and Engineering. 1994; 12: p. 9 - 23.
Ana M.S.Maia, Marta Costa. Redouane Borsali, Rosangela B. Garcia, Macromol. Sym. 2005: p. 217 - 227.
G.A.Stahl, A.Moradi-Araghi, P.H.Doe. High temperature and hardness stable copolymers of vinylpyrrolidone and acrylamide. Water-Soluble Polymer for Petroleum Recovery. 1988: p. 121 - 130.
W.M.Kulicke N.Böse, M.Bouldin. The role of polymers in enhanced oil recovery. Water-Soluble Polymer for Petroleum Recovery. 1988: p. 1 - 18
1. The Author assigns all copyright in and to the article (the Work) to the Petrovietnam Journal, including the right to publish, republish, transmit, sell and distribute the Work in whole or in part in electronic and print editions of the Journal, in all media of expression now known or later developed.
2. By this assignment of copyright to the Petrovietnam Journal, reproduction, posting, transmission, distribution or other use of the Work in whole or in part in any medium by the Author requires a full citation to the Journal, suitable in form and content as follows: title of article, authors’ names, journal title, volume, issue, year, copyright owner as specified in the Journal, DOI number. Links to the final article published on the website of the Journal are encouraged.