Production of green gasoline and light olefins by cracking of triglyceride-rich biomass over nano-ZSM-5/SBA-15 analog composites with variable Si/Al ratios
Keywords:
Nano-ZSM-5, SBA-15 analog, Si/Al ratio, green gasoline, light olefins
Abstract
Nano-ZSM-5/SBA-15 analog composites (ZSC) with different Si/Al molar ratios were prepared and their performance was evaluated in catalytic cracking of triglyceride-rich biomass. It was found that the initial Si/Al ratio used in the synthesis mixture performance of ZSC catalysts in catalytic cracking of triglyceride-rich biomass.
References
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2. G.W.Huber, A.Corma. Synergies between bio- and oil refineries for the production of fuels from biomass. Angewandte Chemie International Edition. 2007; 46(38): p. 7184 - 7201.
3. K.D.Maher, D.C.Bressler. Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals. Bioresource Technology. 2007; 98(12): p. 2351 - 2368.
4. R.O.Idem, S.P.R.Katikaneni, N.N.Bakhshi. Catalytic conversion of canola oil to fuels and chemicals: roles of catalyst acidity, basicity and shape selectivity on product distribution. Fuel Processing Technology. 1997; 51(1, 2): p. 101 - 125.
5. D.Chen, N.I.Tracy, D.W.Crunkleton, G.L.Price. Comparison of canola oil conversion over MFI, BEA, and FAU. Applied Catalysis A: General. 2010; 384(1, 2): p. 206 - 212.
6. F.A.Twaiq, N.A.M.Zabidi, S.Bhatia. Catalytic conversion of palm oil to hydrocarbons: performance of various zeolite catalysts. Industrial Engineering Chemistry Research. 1999; 38(9): p. 3230 - 3237.
7. S.P.R.Katikaneni, J.D.Adjaye, R.O.Idem, N.N.Bakhshi. Catalytic conversion of canola oil over potassiumimpregnated HZSM-5 catalysts: C2-C4 olefin production and model reaction studies. Industrial Engineering Chemistry Research. 1996; 35(10): p. 3332 - 3346.
8. J.A.Botas, D.P.Serrano, A.Garcia, R.Ramos. Catalytic conversion of rapeseed oil for the production of raw chemicals, fuels and carbon nanotubes over Ni-modified nanocrystalline and hierarchical ZSM-5. Applied Catalysis B: Environmental. 2014; 145: p. 205 - 215.
9. Vu Xuan Hoan, Nguyen Sura, Dang Thanh Tung, Phan Minh Quoc Binh, Nguyen Anh Duc, U.Armbruster, A.Martin. Catalytic cracking of triglyceride-rich biomass toward lower olefins over a Nano-ZSM-5/SBA-15 analog composite. Catalysts. 2015; 5(4): p. 1692 - 1703.
10. Z.Nawaz, T.Xiaoping, F.Wei. Influence of operating conditions, Si/Al ratio and doping of zinc on Pt-Sn/ZSM-5 catalyst for propane dehydrogenation to propene. Korean Journal of Chemical Engineering. 2009; 26(6): p. 1528 - 1532.
11. X.Zhu, S.Liu, Y.Song, L.Xu. Catalytic cracking of C4 alkenes to propene and ethene: Influences of zeolites pore structures and Si/Al2 ratios. Applied Catalysis A: General. 2005; 288(1 - 2): p. 134 - 142.
12. Vu Xuan Hoan, U.Bentrup, M.Hunger, R.Kraehnert, U.Armbruster, A.Martin. Direct synthesis of nanosized-ZSM-5/SBA-15 analog composites from preformed ZSM-5 precursors for improved catalytic performance as cracking catalyst. Journal of Materials Science. 2014; 49(16): p. 5676
- 5689.
13. C.H.Cheng, G.Juttu, S.F.Mitchell, D.F.Shantz. Synthesis, characterization and growth rates of aluminumand Ge, Al-substituted silicalite-1 materials grown from clear solutions. Journal Of Physical Chemistry B. 2006; 110(45): p. 22488 - 22495.
14. Q.Li, Z.Wu, B.Tu, S.S.Park, C.S.Ha, D.Zhao. Highly hydrothermal stability of ordered mesoporous
aluminosilicates Al-SBA-15 with high Si/Al ratio. Microporous And Mesoporous Materials. 2010; 135(1 - 3): p. 95 - 104.
15. A.Ungureanu, B.Dragoi, V.Hulea, T.Cacciaguerra, D.Meloni, V.Solinas, E.Dumitriu. Effect of aluminium incorporation by the “pH-adjusting” method on the structural, acidic and catalytic properties of mesoporous SBA-15. Microporous and Mesoporous Material. 2012; 163: p. 51 - 64.
16. Z.Luan, J.A.Fournier. In situ FTIR spectroscopic investigation of active sites and adsorbate interactions in mesoporous aluminosilicate SBA-15 molecular sieves. Microporous and Mesoporous Material. 2005; 79(1 - 3): p. 235 - 240.
17. M.Stocker. Gas phase catalysis by zeolites. Microporous and Mesoporous Material. 2005; 82(3): p. 257 - 292.
18. Vu Xuan Hoan, M.Schneider, U.Bentrup, Dang Thanh Tung, Phan Minh Quoc Binh, Nguyen Anh Duc, U.Armbruster, A.Martin. Hierarchical ZSM-5 materials for an enhanced formation of gasoline-range hydrocarbons and light olefins in catalytic cracking of triglyceride-rich biomass.
Industrial and Engineering Chemistry Research. 2015; 54(6): p. 1773 - 1782.
Published
2016-06-30
How to Cite
Hoan, V. X., Sura, N., Tung, D. T., Binh, P. M. Q., Duc, N. A., Hunger, M., Armbruster, U., & Martin, A. (2016). Production of green gasoline and light olefins by cracking of triglyceride-rich biomass over nano-ZSM-5/SBA-15 analog composites with variable Si/Al ratios. Petrovietnam Journal, 6, 42-49. Retrieved from http://www.pvj.com.vn/index.php/TCDK/article/view/525
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