CO2-CH4 exchange in the context of CO2 injection and gas production from methane hydrates bearing sediments
Keywords:
Methane hydrates
Abstract
In recent decades, scientists have made an amazing discovery: Methane hydrates in the ocean floor. These solid compounds could represent an important energy reserve. Today it is estimated that they contain equivalent carbon in the form of methane in a huge quantity, twice as much as all deposits of natural gas, oil and coal.
In the near future, we need evaluate the possibility to produce this new source of energy, particularly in replacement of oil and coal. The main question concerns the technology to be used because the methane hydrates are distributed in sediment, and they participate to their consolidation.
In this paper, we present a method which doesn’t modify the structure of the sediment, by replacing the methane hydrate by CO2, hydrate after injection of CO2, gas.
References
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21. J.M.Herri, A.Bouchemoua, M.Kwaterski, A.Fezoua, Y.Ouabbas, A.Cameirao. Gas hydrate equilibria from CO2N2, and CO2-CH2 gas mixtures, experimental studies and thermodynamic modelling. Fluid Phase Equilibria. 2011; 301: р. 171 - 190.
22. J.M.Herri, E.Chassefiere. Carbon dioxide, argon, nitrogen and methane clathrate hydrates: Thermodynamic modelling, investigation of their stability in Martian atmospheric conditions and variability of methane trapping. Accepted to planetary and space sciences. 2012.
23. J.M.Herri, M.Kwaterski. Derivation of a Langmuir type of model to describe the intrinsic growth rate of gas hydrates during crystallization from gas mixtures. Chemicalf Engineering Science. 2012; 81: p. 28 - 37.
24. J.M.Herri, H.Le Ba, A.Cameirao, M.Darbouret, J.L.Peytavy, P.Glenat. interpretation and modeling of chord length distribution from FBRM results during gas hydrate formation and agglomeration from water-in-oil emulsion.Abstracts of papers of the American chemical society.Meeting Abstract: 106-FUEL. 2009; 237.
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27. N.Hamed. Etude de la cinétique de formation des hydrates de méthane dans les fluides de forage off-shore par analyse calorimétrique différentielle haute pression. Thése de doctorat: Génie des Procédés, ENSMP. 2006.
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29. A.GJones, J.Hostomsky, Zhou Li. On the effect of liquid mixing rate on primary crystal size during the gas-liquid precipitation of calcium carbonate. Chemical Engineering Science. 1992; 47.
30. KA Kvenvolden. Gas hydrates – geological perspective and global change. Reviews of Geophysics. 1993; 31: р. 173 - 187.
31. M.Kwaterski, and J.M.Herri. Modelling Gas Hydrate Equilibria using the Electrolyte Non-Random Two-Liquid (eNTRL) Model. Submitted to Fluid Phase Equilibria. 2012.
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34. V.McKoy, O.Sinanoglu. Theory of dissociation pressures of some gas hydrates. J. Chem. Phys. 1963; 38.
35. G.Naval. in situ methane hydrate dissociation with carbon dioxide sequestration: Current knowledge and issues. Journal of Petroleum Science and Engineering. 2006; 51(3 - 4): р. 169 - 184.
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37. D.Nguyen Hong, FChauvy, J.M.Herri. CO2, - “Capture by hydrate crystallization - A potential solution for gas emission of steelmaking industry”. Energy Conversion and Management. 2007; 48: p. 1313 - 1322.
38. D.Nguyen Hong, F.Gruy, J.M.Herri. An analytical estimation for dissociation time of hydrate plugs in pipelines. Chemical Engineering Science. March 2006; 61(6): p. 1846 - 1853.
39. M.Ota, Y.Abe, M.Watanabe, R.LJrSmith and H.Inomata. Methane recovery from methane hydrate using pressurized CO2. Fluid Phase Equilibria. 2005; 228 - 229: р. 553-559.
40. M.Ota, K.Morohashi, Y.Abe, M.Watanabe, R.L.Jr. Smith and H.Inomata. Replacement of CH, in the hydrate by use of liquid CO2., Energy Conversion and Management. 2005; 46(11 - 12): p. 1680 - 1691.
41. J.S.Pic, J.M.Herri, M.Cournil. Experimental influence of kinetic inhibitors on methane hydrate particle size distribution during batch crystallization. Canadian Journal of Chemical Engineering. 2001: 79(3), p. 374 - 383.
42. J.S.Pic, J.M.Herri, M.Cournil. Mechanisms of methane hydrate crystallization in a Semi-batch reactor: Influence of a kinetic inhibitor (PolyVynilPyrrolidone). Annals of the New York Academy of Sciences. 2000; 912: p. 564 - 575.
43. Jy.Ribeiro, PClaudio, PL.C.Lage. Modelling of hydrate formation kinetics: State-of-the-art and future directions. Chem. Eng. Sci. 2008; 63, 2007 - 2034.
44. E.D.Sloan. Gas hydrate current status assessment of resource and simulation based evaluation of technology and potential. 2010.
45. E.D.Sloan. Fundamental principles and applications of natural gas hydrates. Nature. 2003; 46: p.353-359.
46. E.D.Sloan, C.A.Koh. Clathrate Hydrates of Natural Gases. CRC Press, Taylor & Francis Group, Boca Raton, London, New York, 3rd ed. 2008.
47. E.D.Sloan. Clathrate hydrates of natural gases. 2nd ed. Marcel Decker, New York. 1998.
48. S.LSmith, ASJudge. Estimates of methane hydrate volumes in the Beaufort-Mackenzie region, Northwest Territories, in Current Research. Geological survey of Canada, 81-88 (also Geological survey of Canada open file 2746, 1993), 1995.
49. SSolomon, D.M.Qin, Z.Manning, M.Chen, K.B.Marquis, M.Averyt, H.L.Miller. Contribution of working group I to the Fourth Assessment Report of the intergovernmental panel on climate change. Cambridge University Press, Cambridge, UK, and New York, NY, USA; Table 2.14, Chap. 2, 212. 2007.
50. E.Suess, G.Bohrman, J.Greinert, E.Lausch. Le méthane dans les océans. Pour la Science. October 1999; 264.
51. KTakahashi, N.Sakai. hydrate de méthane, la source dénergie de demain dormant sous le fond océanique. Japan National Oil Corporation, Reportage spécial. 2004.
52. N.Tonnet. Dissociation des hydrates de methane sedimentaires couplage transfert de chaleur /transfert de masse. Thése de doctorat: Génie des Procédés, ENSMSE. 2007.
53. N.Tonnet and J.M.Herri. Methane hydrates bearing synthetic sediments - Experimental and numerical approaches of the dissociation. Chemical Engineering Science. 2009; 64(19): p. 4089 - 4100.
54. G.K.Westbrook, B.Carson, R.J.Musgrave. Proceedings of the ocean drilling. 1994.
55. MD.White, SK.Wurstner and BP.McGrail. Numerical studies of methane production from Class 1 gas hydrate accumulations enhanced with carbon dioxide injection. Marine and Petroleum Geology. 2011; 28(2): p. 546 - 560.
56. Yoshitaka, O.Michca, K.Taro, T.Tomoya and T.Yuichi. Thermal conductivity measurement of methane hydrates with soil. Proceedings of the 6th International Conference on Gas Hydrates, ICGH. 2008.
2. O.Bonnefoy, F.Gruy, J.M.Herri. Calculation of the index of refraction and Hamaker constant of gas hydrates, Materials chemistry and physics. 2005; 89(2 - 3): p. 336 - 344.
3. O.Bonnefoy, F.Gruy, J.M.Herri. Van der Waals interactions in systems involving gas hydrates. Fluid phase equilibrium. 2005; 231(2): p. 176 - 187.
4. O.Bonnefoy. influence de cristaux d’hydrates de gaz ou de glace sur la perméabilité d’un milieu poreux. Thése de doctorat: Génie des Procédés, ENSMSE. 2005.
5. A.Bouchemoua, A.Thiam, A.B.Fezoua, Y.Ouabbas, F.Chauvy, A.Cameirao, J.M. Herri. Cinétique de croissance des d’hydrates mixtes de CO, CRISTAL 6, Numéro 99, 2-910239-73-x, Ed. SFGP Paris, France. 2010.
6. A.Cameirao, H.Le Ba, M.Darbouret, J.M.Herri, J.L.Peytavy, PGlénat. Chord length distributions interpretation using a polydispersed population: Modeling and experiments. Journal of Crystal Growth. 2012; 342: p. 65 - 71.
7. E.Chassefiére, E.Dartois, J.M.Herri, F.Tian, O.Mousis, A.Lakhlifi, FSchmidt. Climate consequences of CO2,-SO2, clathrate hydrate formation on early Mars. Submitted to earth and planetary science letters. 2012.
8. M.Cournil, J.M.Herri. Asymptotic model for gas-liquid crystallization in two-film systems. A.I.Ch.E. 2003; 49 (8): p. 2030 - 2038.
9. M.Darbouret, M.Coumil, J.M.Herri. Rheological study of TBAB hydrate slurries as secondary two-phase refrigerants. International Journal of Refrigeration. 2005; 28(5): p. 663 - 671.
10. J.Douzet, A.Lallemand, F.Chauvy,J.M.Herri, D.Flick. Prototyping a real size air conditioning system using a TBAB hydrate slurry as secondary two phase refrigerants. Experimental and modelling results. Submitted to International Journal of Refrigeration. 2012.
11. PEnglezos, N.Kalogerakis, P.D.Dholabhai, PR.Bishnoi. Kinetics of formation of methane and ethane gas hydrates. Chemical Engineering Science. 1987; 42(11), p. 2647 - 2658.
12. PEnglezos. Chlathrate hydrates. Ind. Eng. Chem. Res. 1993; 32: p. 1251 - 1274.
13. A.Eslamimanesh, A.H.Mohammadi, D.Richon, PNaidoo, D.Ramjugernath. Application of gas hydrate formation in separation processes: A review of experimental studies. J. Chem. Thermodynamics. 2012; 46: p. 62 - 71.
14. A.Fidel-Dufour, F.Gruy, J.M.Herri. Experimental characterization and modelling of the rheological properties of methane hydrate slurries during their crystallization in a water in dodecane emulsion under laminar flowing. Chemical Engineering Science. 2005; 61: p.505 - 515.
15. A.Fezoua, A.Bouchemoua, Y.Quabbas, F.Chauvy, A.Cameirao, J.M. Herri. Captage du CO, par voie hydrate: Étude de la cinétique de formation des hydrates dans une émulsion eau dans Fhuile. CRISTAL 6, Numéro 99 – 2010 2-910239-73-x, Ed. SFGP, Paris, France. 2010.
16. A.Galfré, A.Cameirao, FChauvy, A.Lallemand, J.M.Herri. Clathrate hydrates equilibrium points for carbon dioxide and nitrogen gas mixture in presence of cyclopentane in water emulsion. Under preparation to Chem. Engineering. Science, 2012.
17. G.Ersland. Studies of flow mechanisms and hydrate phase transitions in fracture rocks. Dissertation for the degree philosophiae doctor at the University of Bergen. 2008.
18. J.M.Herri, FGruy. Calculation of the index of refraction of pure hydrate gaz using a modified Lorentz- Lorenz model: application to methane hydrate. Materials chemistry and physics. 1995; 42: p. 51-55.
19. J.M.Herri, FGruy, J.S.Pic, M.Cournil, B.Cingotti, A.Sinquin. Interest of in situ particle size determination for the characterization of methane hydrate formation. Application to the study of kinetic inhibitors. Chemical Engineering Science. 1999; 54(1 2): p. 1849 - 1858.
20. JM.Herri, FGruy, J.S.Pic, M.Cournil. Methane hydrate crystallisation Mechanism from in situ particle sizing. A.I.Ch.E. Journal. 1999; 45(3): p. 590 - 602.
21. J.M.Herri, A.Bouchemoua, M.Kwaterski, A.Fezoua, Y.Ouabbas, A.Cameirao. Gas hydrate equilibria from CO2N2, and CO2-CH2 gas mixtures, experimental studies and thermodynamic modelling. Fluid Phase Equilibria. 2011; 301: р. 171 - 190.
22. J.M.Herri, E.Chassefiere. Carbon dioxide, argon, nitrogen and methane clathrate hydrates: Thermodynamic modelling, investigation of their stability in Martian atmospheric conditions and variability of methane trapping. Accepted to planetary and space sciences. 2012.
23. J.M.Herri, M.Kwaterski. Derivation of a Langmuir type of model to describe the intrinsic growth rate of gas hydrates during crystallization from gas mixtures. Chemicalf Engineering Science. 2012; 81: p. 28 - 37.
24. J.M.Herri, H.Le Ba, A.Cameirao, M.Darbouret, J.L.Peytavy, P.Glenat. interpretation and modeling of chord length distribution from FBRM results during gas hydrate formation and agglomeration from water-in-oil emulsion.Abstracts of papers of the American chemical society.Meeting Abstract: 106-FUEL. 2009; 237.
25. H.Le Ba. Formation et agglomération de particules d‘hydrate de gaz dans une émulsion eau dans huile: Etude expérimentale et modélisation. Thèse de doctorat: Génie des Procédés, ENSMSE. 2009.
26. H.Le Ba, A.Cameirao, J.M.Herri, M.Darboure, J.L.Peytavy, P.Glénat, Chord. Length distributions measurements during crystallisation and agglomeration of gas hydrate in a water-in-oil emulsion: Simulation and experimentation. Chemical Engineering Science. 2010; 65(3): p. 1185 - 1200.
27. N.Hamed. Etude de la cinétique de formation des hydrates de méthane dans les fluides de forage off-shore par analyse calorimétrique différentielle haute pression. Thése de doctorat: Génie des Procédés, ENSMP. 2006.
28. GAJeffrey. Inclusion compounds. Academic Press, New York. 1984; 1.
29. A.GJones, J.Hostomsky, Zhou Li. On the effect of liquid mixing rate on primary crystal size during the gas-liquid precipitation of calcium carbonate. Chemical Engineering Science. 1992; 47.
30. KA Kvenvolden. Gas hydrates – geological perspective and global change. Reviews of Geophysics. 1993; 31: р. 173 - 187.
31. M.Kwaterski, and J.M.Herri. Modelling Gas Hydrate Equilibria using the Electrolyte Non-Random Two-Liquid (eNTRL) Model. Submitted to Fluid Phase Equilibria. 2012.
32. J.Leggett. Global Warming: The Greenpeace Repor. Oxford University press, Oxford, U.K. 1990: p. 4- 41.
33. B.P.McGrai, H.T.Schaef, M.D.White, T.Zhu, AS.Kulkarni, R.B.Hunter, SL.Patl, ATOwen and P.F.Martin. Using carbon dioxide to enhance recovery off methane from gas hydrate reservoirs. Final Summary Report. PNNL-17035, Pacific Northwest National Laboratory, Richland, WA. 2007.
34. V.McKoy, O.Sinanoglu. Theory of dissociation pressures of some gas hydrates. J. Chem. Phys. 1963; 38.
35. G.Naval. in situ methane hydrate dissociation with carbon dioxide sequestration: Current knowledge and issues. Journal of Petroleum Science and Engineering. 2006; 51(3 - 4): р. 169 - 184.
36. D.Nguyen Hong, J.M.Herri.A global view of hydrate technology in the world - its application and development potential in the Viet Nam. Science and Technology. 2006; 15/16.
37. D.Nguyen Hong, FChauvy, J.M.Herri. CO2, - “Capture by hydrate crystallization - A potential solution for gas emission of steelmaking industry”. Energy Conversion and Management. 2007; 48: p. 1313 - 1322.
38. D.Nguyen Hong, F.Gruy, J.M.Herri. An analytical estimation for dissociation time of hydrate plugs in pipelines. Chemical Engineering Science. March 2006; 61(6): p. 1846 - 1853.
39. M.Ota, Y.Abe, M.Watanabe, R.LJrSmith and H.Inomata. Methane recovery from methane hydrate using pressurized CO2. Fluid Phase Equilibria. 2005; 228 - 229: р. 553-559.
40. M.Ota, K.Morohashi, Y.Abe, M.Watanabe, R.L.Jr. Smith and H.Inomata. Replacement of CH, in the hydrate by use of liquid CO2., Energy Conversion and Management. 2005; 46(11 - 12): p. 1680 - 1691.
41. J.S.Pic, J.M.Herri, M.Cournil. Experimental influence of kinetic inhibitors on methane hydrate particle size distribution during batch crystallization. Canadian Journal of Chemical Engineering. 2001: 79(3), p. 374 - 383.
42. J.S.Pic, J.M.Herri, M.Cournil. Mechanisms of methane hydrate crystallization in a Semi-batch reactor: Influence of a kinetic inhibitor (PolyVynilPyrrolidone). Annals of the New York Academy of Sciences. 2000; 912: p. 564 - 575.
43. Jy.Ribeiro, PClaudio, PL.C.Lage. Modelling of hydrate formation kinetics: State-of-the-art and future directions. Chem. Eng. Sci. 2008; 63, 2007 - 2034.
44. E.D.Sloan. Gas hydrate current status assessment of resource and simulation based evaluation of technology and potential. 2010.
45. E.D.Sloan. Fundamental principles and applications of natural gas hydrates. Nature. 2003; 46: p.353-359.
46. E.D.Sloan, C.A.Koh. Clathrate Hydrates of Natural Gases. CRC Press, Taylor & Francis Group, Boca Raton, London, New York, 3rd ed. 2008.
47. E.D.Sloan. Clathrate hydrates of natural gases. 2nd ed. Marcel Decker, New York. 1998.
48. S.LSmith, ASJudge. Estimates of methane hydrate volumes in the Beaufort-Mackenzie region, Northwest Territories, in Current Research. Geological survey of Canada, 81-88 (also Geological survey of Canada open file 2746, 1993), 1995.
49. SSolomon, D.M.Qin, Z.Manning, M.Chen, K.B.Marquis, M.Averyt, H.L.Miller. Contribution of working group I to the Fourth Assessment Report of the intergovernmental panel on climate change. Cambridge University Press, Cambridge, UK, and New York, NY, USA; Table 2.14, Chap. 2, 212. 2007.
50. E.Suess, G.Bohrman, J.Greinert, E.Lausch. Le méthane dans les océans. Pour la Science. October 1999; 264.
51. KTakahashi, N.Sakai. hydrate de méthane, la source dénergie de demain dormant sous le fond océanique. Japan National Oil Corporation, Reportage spécial. 2004.
52. N.Tonnet. Dissociation des hydrates de methane sedimentaires couplage transfert de chaleur /transfert de masse. Thése de doctorat: Génie des Procédés, ENSMSE. 2007.
53. N.Tonnet and J.M.Herri. Methane hydrates bearing synthetic sediments - Experimental and numerical approaches of the dissociation. Chemical Engineering Science. 2009; 64(19): p. 4089 - 4100.
54. G.K.Westbrook, B.Carson, R.J.Musgrave. Proceedings of the ocean drilling. 1994.
55. MD.White, SK.Wurstner and BP.McGrail. Numerical studies of methane production from Class 1 gas hydrate accumulations enhanced with carbon dioxide injection. Marine and Petroleum Geology. 2011; 28(2): p. 546 - 560.
56. Yoshitaka, O.Michca, K.Taro, T.Tomoya and T.Yuichi. Thermal conductivity measurement of methane hydrates with soil. Proceedings of the 6th International Conference on Gas Hydrates, ICGH. 2008.
Published
2012-10-31
How to Cite
Duyen, L. Q., Herri, J.-M., Ouabbas, Y., Nam, T. H., & Du, L. Q. (2012). CO2-CH4 exchange in the context of CO2 injection and gas production from methane hydrates bearing sediments. Petrovietnam Journal, 10, 38-45. Retrieved from https://www.pvj.com.vn/index.php/TCDK/article/view/1002
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